Liquid–liquid extraction of tantalum with 2-octanol

Tantalum extraction being performed at the recommended conditions provides the ratio of tantalum/niobium distribution coefficients to be at least 200–250 that ensure separation using a multistage process for extraction, washing and stripping. 2-Octanol does not extract main impurities such as titanium, iron and manganese from an …

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Reducing agents in the leaching of manganese ores: A comprehensive

Quantitative dissolution of both manganese (99.9%) and nickel (98.9%), with no tantalum dissolution, was witnessed under the optimized leaching condition of 3 M HCl, 50 g/l pulp density, 60 °C ...

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A review on extractive metallurgy of tantalum and …

The extraction of these two metals from ore deposits and secondary resources is based on the generic extractive metallurgical techniques known from the …

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Study on hydrometallurgical process and kinetics of manganese

2.2. Experimental procedure. Firstly, 300 g ore sample (size of below 2 mm) and 300 mL water were grinded by ball-milling for a certain time.In each leaching test, the weight of manganese ore was maintained constant at 300 g.Then, the pulp was diluted to a certain density and put in a 2 L glass vessel, and a certain proportion of sulfuric acid was …

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Recovery of Tantalum and Manganese from

Explore millions of resources from scholarly journals, books, newspapers, videos and more, on the ProQuest Platform.

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(PDF) Hydrometallurgical Process for Tantalum Recovery …

order to separate tantalum and manganese, a solvent extraction process was conducted. In the solvent extraction experiment, the concentrations of Ta and Mn wer e diluted to 1000 mg / L and 150 mg / L,

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Hybrid leaching of tantalum and other valuable metals from tantalum

The transition metal tantalum is a hard, blue-grey element with a refectory character, high density and dielectric strength with a very low coefficient of thermal expansion (6.4 × 10 −6 [m/(m·K)] at 20 °C). Tantalum due to its specific physical and chemical properties has many technological applications, but it is indispensable as part …

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Manganese | Elements | RSC Education

Manganese steel contains around 13% manganese and was patented in 1883 by Robert Hadfield, a metallurgist from Sheffield, UK. It is extremely strong and is used for railway tracks, safes and prison bars. …

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An investigation on hydrofluoric (HF) acid-free extraction …

Tantalum, niobium, and their oxides are important precursor materials, essential for high-temperature alloys and electronic devices. The primary hydrometallurgical extraction technique to extract tantalum and niobium from minerals involves hydrofluoric acid (HF) digestion of the concentrates, followed by solvent extraction as an oxide …

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Efficient Recovery of Niobium and Tantalum from

Abstract A stable and continuous leaching process for niobium and tantalum extraction from ferrocolumbium tantalum (FT) was developed. The effects of initial concentration of HF and H2SO4, grinding fineness, leaching time, and temperature on the leaching rate of Ta, Nb, Fe, and Si were studied. Experimental results show that the …

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A review of tantalum resources and its production

The extraction system still requires further study to unravel the extraction mechanism, identify the optimum conditions and to find solutions to the problem of third-phase generation. 4.3 Preparation of tantalum Though tantalum metal can be produced by several means, only two processes, namely sodium reduction of K2TaF7 and salt …

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Tantalum Mining | Processing Equipment | Flow Chart

20TPH Tantalum Niobium Mining Plant in Uganda. Material: Tantalum Niobium Capacity: 20TPH Country: Uganda Max. Feeding size: 0-50mm Raw mineral description: 1. Mineral composition: tantalum niobium 2. Particle size distribution: 0-30mm takes 85-90% 3. Raw ore contains agglomerate slime. Customers requirements: increase the tantalum …

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A review on extractive metallurgy of tantalum and niobium

Quantitative dissolution of both manganese (99.9%) and nickel (98.9%), with no tantalum dissolution, was witnessed under the optimized leaching condition of 3 M HCl, 50 g/l pulp density, 60 °C ...

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Recovery of niobium and tantalum by solvent …

ore is columbo tantalite, the source of the strategic coltan. In this work the raw material (slag) has been treated by acid leaching, using HF/H 2SO 4 as the leaching agent. Then …

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Recovery of Tantalum and Manganese from Epoxy-Coated …

1. Introduction. The demand for tantalum capacitors is steadily increasing due to the popularity of small electronic products. At the same time, small electronic products are eliminated rapidly, which represents a large amount of waste [1,2,3].Tantalum is a transition element with an atomic number of 73, an atomic weight of 180.95, and a melting point of …

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New approaches to niobium and tantalum extraction technology

Spent epoxy-coated solid electrolyte tantalum capacitors, containing about 22 wt.% of tantalum and 8 wt.% of manganese, were treated with selective leaching by hydrochloric acid and chlorination ...

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Review on metal extraction technologies suitable for critical …

The extraction of critical metals in a circular mining system begins with mineral processing (Fig. 2).Mineral processing involves liberating and concentrating economical metals and minerals from a mined resource using comminution (particle size reduction), classification (particle size screening), and separation technologies (e.g., …

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Solvent extraction equilibrium study of manganese(II) …

The single-stage extraction of manganese(II) sulphate with Cyanex 302 in kerosene (O:A = 1:1) has been studied.The pH 50 values are 5.75, 5.35, 5.20 and 4.15 for 0.025, 0.05, 0.07 and 0.1 M Cyanex 302, respectively. The mechanism of extraction and stoichiometries of metal-containing extracted species has been established on the basis …

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Hybrid leaching of tantalum and other valuable …

The removal of manganese from the tantalum capacitor scrap will not only contribute to resource recovery but is also an important step in tantalum recycling …

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Recovery of niobium and tantalum by solvent …

First published on 5th June 2020. Abstract. The slag from the extraction processes of metals from their ores may contain valuable components that, if adequately recovered, …

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Hydrometallurgical recovery of manganese and …

Hydrometallurgical route for selective dissolution of manganese and nickel from tantalum capacitors, isolating tantalum into the residue, followed by selective …

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Overview Tantalum-Processing, Properties and …

Table II. Extraction of Tantalum Metal tantalum in a more or less pulverized form. Table III shows the chemical compositions of raw tantalum from different reduction processes.2,9 …

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Extraction of niobium and tantalum from ferrocolumbite

Pressure acid leaching was used to extract niobium and tantalum from a ferrocolumbite ore. The leaching was carried out in a pressure reactor using hydrofluoric acid as leachant. Various parameters, such as temperature, reaction time, HF concentration, stirring speed, particle size and solid-to-liquid ratio in the leaching …

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A review of tantalum resources and its production

Tin slag was once an important raw material for primary tantalum production in some countries, such as Thailand, Malaysia, and Brazil. Tantalum extracted from tin …

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Tantalum in the environment

There are many tantalum minerals, but the number which have been used by industry as raw materials so far is quite limited (Table 3). Tantalite (Fe,Mn)Ta 2 O 6 is the most important mineral for tantalum extraction. Due to lanthanide contraction and hence their similar properties, niobium and tantalum replace each other isomorphically in …

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Hydrometallurgical Processing of Manganese Ores: A …

Quantitative dissolution of both manganese (99.9%) and nickel (98.9%), with no tantalum dissolution, was witnessed under the optimized leaching condition of 3 M HCl, 50 g/l pulp density, 60 °C ...

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Hydrometallurgical recovery of manganese and nickel and

Hydrometallurgical route for selective dissolution of manganese and nickel from tantalum capacitors, isolating tantalum into the residue, followed by selective recovery of manganese over nickel using solvent extraction was investigated. 3 M HCl with 100 g/l pulp density at 60 °C for 120 min were found to be the optimal parameters for …

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EC names critical, strategic raw materials under proposed …

Importantly, the proposed Act now formally defines the new category of "strategic." It states the list of strategic raw materials "should contain raw materials that are of high strategic importance, taking into account their use in strategic technologies underpinning the green and digital transitions or for defence or space applications, that …

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Liquid–liquid extraction of tantalum with 2-octanol

Initial experimental conditions were as follows: Initial solution: Ta2O5, 86.7 g/l; H2SO4, 3 M; organic: aqueous volume ratio (Vorg:Vaqu.): extraction, 2:1; washing, 10:1; stripping, 3:1. The ...

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Tantalum

Processing: Extraction and Refining. K 2 TaF 7 Process, H.C. Starck , (Gerald Baehnish) The extraction and refining of tantalum, including the separation from niobium in these various tantalum-containing mineral concentrates, is generally accomplished by treating the ores with a mixture of hydrofluoric and sulfuric acids at elevated …

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(PDF) Extraction of Niobium from Tin Slag

Recovery % = 6.7/25 x 100 = 26.8% This is a good result as far as extraction of niobium is concerned. The density of niobium obtained by the displacement in water is: Density = mass/volume 6.7/0.82 = 8.17g/cm3 Therefore to obtain the percentage purity, the theoretical density of the niobium at 20oC is 8.57g/m3.

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Tantalum Metallurgy | SpringerLink

Tantalum metallurgy is the technology to extract tantalum metal from tantalum-bearing material. In 1802, the Swedish chemist A.G. Ekeberg discovered a new element in tantalite and named it tantalum, which was derived from Tantalus, son of Zeus of Greek mythology. A German named H. Rose proved in 1844 that niobic acid and …

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Tantalum Processing | TIC

Processing: extraction and refining. K2TaF7 Process, H.C. Starck , (Gerald Baehnish) The extraction and refining of tantalum, including the separation from niobium in these various tantalum-containing mineral concentrates, is generally accomplished …

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Extractive metallurgy of columbite-tantalite ore: A detailed …

The increased demand of metals such as tantalum (Ta) and niobium (Nb) reflect the on-going development in modern science, engineering and technology. The extraction of these two metals from columbite-tantalite ore is based on generic extractive metallurgy. However, the upstream purification of ore and downstream extraction of Ta …

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Separation of manganese and nickel from tantalum

The experimental data of zinc and manganese extraction in pH range of 1–5, temperature of 23, 40 and 60°C and different organic phase composition (D2EHPA and Cyanex 302) were used to propose ...

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Separation of manganese and nickel from tantalum

Manganese extraction using phosphoric acid derivatives is typically accomplished through a cation-exchange mechanism [13], [15]. Despite the significant application of these extractants in various scenarios, their specific performance has not been compared in the context of tantalum capacitor leach solutions.

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Critical raw materials: Is Europe ready to go back to the …

raw materials and diversifying import dependencies is crucial for Europe. The CRM Act proposes a 10% target for EU sourcing, but we find that seven out of the 18 materials listed do not meet the requirement at the mining stage (antimony, borate, manganese, natural graphite, rare-earth elements, tantalum and titanium). For all of

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